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Functional Hydrogels for Aqueous Zinc-Based Batteries: Progress and Perspectives.

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  • 1School of Chemical Engineering, Faculty of Sciences, Engineering and Technology, The University of Adelaide, Adelaide, SA, 5005, Australia.

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Summary

Functional hydrogels offer a promising solution for advancing aqueous zinc batteries (AZBs) by addressing electrode, electrolyte, and interface challenges. This review summarizes hydrogel properties, modification strategies, and future directions for grid-scale energy storage.

Keywords:
aqueous zinc‐batteriesfull life cyclehydrogelsinterfacemultifunctionality

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Aqueous zinc batteries (AZBs) are promising for grid-scale energy storage due to cost-effectiveness, safety, and eco-friendliness.
  • Practical AZB deployment faces hurdles in electrode, electrolyte, and interface performance.
  • Functional hydrogels present a viable solution with tunable properties and electrochemical stability.

Purpose of the Study:

  • To review essential properties of functional hydrogels for AZB advancement.
  • To explore modification strategies for enhancing hydrogel properties and AZB performance.
  • To discuss challenges and future directions for industrial AZB implementation.

Main Methods:

  • Literature review of functional hydrogels in aqueous zinc batteries.
  • Analysis of hydrogel properties: mechanical strength, ionic conductivity, swelling, and degradability.
  • Exploration of modification techniques and integration strategies.

Main Results:

  • Key hydrogel properties crucial for AZB performance across their lifecycle are identified.
  • Current strategies for improving hydrogel properties and AZB performance are summarized.
  • Challenges in hydrogel-electrode/interface integration are discussed.

Conclusions:

  • Functional hydrogels are critical for overcoming AZB limitations.
  • Further research and development are needed to bridge the gap between lab-scale findings and industrial application of AZBs.
  • Hydrogel design must consider the full lifecycle for sustainable energy storage solutions.