Surface modification of particles/nanoparticles to improve the stability of Pickering emulsions; a critical review

Pickering emulsions (PEs) are dispersions stabilized by solid particles, which are derived from various materials, both organic (proteins, polysaccharides, lipids) and inorganic (metals, silica, metal oxides). These colloidal particles play a critical role in ensuring the stability and functionality of PEs, making them highly valued across multiple industries due to their enhanced stability and lower toxicity compared to conventional emulsions. The stabilization mechanisms in PEs differ from those in emulsions stabilized by surfactants or biopolymers. The stability of PEs is influenced by intrinsic particle properties, such as wettability, size, shape, deformability, and charge, as well as external conditions like pH, salinity, and temperature. Some particles, especially organic ones, alone may not be effective stabilizers. For instance, many polysaccharides inherently lack surface activity, while most proteins have significant surface activity but often become unstable under environmental stresses, potentially leading to emulsion instability. The chemical composition and morphology of the particles can lead to varying properties, particularly wettability, which plays a vital role in their ability to adsorb at interfaces. As a result, surface modification emerges as an essential approach for improving the effectiveness of particles as stabilizers in PEs. This review presents the mechanisms that stabilize PEs, identifies factors influencing the stability of PEs, and discusses physical and chemical techniques for modifying particle surfaces. There has been a significant advance in understanding surface modification, employing both physical (non-covalent bonds) and chemical (covalent bonds) approaches. These insights are invaluable for optimizing PE formulations, broadening their application potential across various fields.