Utilizing municipal solid waste incineration fly ash for mine goaf filling: Preparation, optimization, and heavy...

Municipal solid waste incineration fly ash (MSWI FA) contains many harmful substances, such as heavy metals, which pose a great threat to the ecological environment. Its proper disposal is an urgent environmental problem that needs to be addressed. The large number of goaf areas in China's mines provides a new approach for MSWI FA treatment. Scientifically processed MSWI FA can be used for goaf filling; this reduces the stockpile of MSWI FA and improves the safety of mine goaf areas. In this study, paste backfill was prepared using MSWI FA and slag as cementitious materials and coal gangue as aggregates under the composite excitation of sodium hydroxide and water glass. The optimal mix ratio was determined using response surface methodology, and the leaching trend of the heavy metal ions inside the material and the micro mechanism of strength formation were studied. Molecular dynamics simulations were used to further examine the leaching pathways of the heavy metal ions. The experimental research showed that the optimal mix proportions of the backfill were 81.65%, 3.67% and 52.27% for the mass concentration, aggregate-to-cement ratio and fine gangue ratio, respectively. The main polymerization products were C-(A)-S-H and N-A-S-H silicate gel, and small amounts of ettringite (AFt), calcium aluminate chloride (3CaO • Al₂O₃ • 3CaCl₂ • 30H₂O) and CaCO₃ were generated. Through Materials Studio (MS) software, the leaching pathway of the heavy metal ions in the backfill and the adsorption performance between the ions were examined, and the influence of the C-A-S-H gel on the leaching rates of the heavy metal ions of Pb²⁺, Cr³⁺, and Cd²⁺ was explored. The leaching rate was ranked as Pb²⁺>Cr³⁺>Cd²⁺. In this study, a pollution-free and structurally stable mine paste backfill material was prepared using MSWI FA solid waste.