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Updated: Jun 4, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Relationship between Transition-Metal Hydride Bond Lengths and Stretching Wavenumbers.

Robert H Morris1

  • 1Department of Chemistry, University of Toronto, 80 Saint George Street, Toronto, Ontario M5S-3H6, Canada.

Inorganic Chemistry
|December 18, 2024
PubMed
Summary

A linear relationship exists between metal hydride bond length and stretching frequency in 3d transition metals. This finding reveals no correlation with bond dissociation free energy, offering new insights into metal-hydride chemistry.

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