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  6. Unveiling The Role Of Sintering Temperatures In The Physical Properties Of Cu-mg Ferrite Nanoparticles For Photocatalytic Application

Unveiling the role of sintering temperatures in the physical properties of Cu-Mg ferrite nanoparticles for photocatalytic application

Sumi Akter1, M N I Khan2, Faria Ferdous3

  • 1Bangladesh University of Engineering and Technology, Dhaka, 1000, Bangladesh.

Heliyon
|December 24, 2024

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View abstract on PubMed

Summary
This summary is machine-generated.

Sintering temperature significantly impacts Cu-Mg nanoferrite properties, influencing structural, magnetic, and optical characteristics. Higher temperatures enhance crystallite size and saturation magnetization, indicating potential for photocatalytic applications.

Area of Science:

  • Materials Science
  • Nanotechnology
  • Solid State Chemistry

Background:

  • Ferrite nanoparticles (NPs) are versatile materials with applications in various fields.
  • Controlling the properties of Cu-MgFe2O4 nanoferrites is crucial for optimizing their performance.
  • The sol-gel method offers a controlled approach for synthesizing nanomaterials.

Purpose of the Study:

  • To investigate the explicit effects of sintering temperature (Ts) on Cu0.5Mg0.5Fe2O4 nanoferrites.
  • To analyze the resulting changes in structural, morphological, magnetic, and optical properties.
  • To evaluate the potential of these nanoferrites in photocatalytic applications.

Main Methods:

  • Synthesis of Cu-Mg ferrite NPs via the sol-gel method.
  • Sintering of NPs at temperatures ranging from 300 to 800 °C.
Keywords:
Magnetic and optical propertiesPhotocatalystSintering temperatureSpinel Cu-Mg nanoferrites

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  • Characterization using Thermogravimetric analysis, XRD, SAED, FTIR, TEM, EDS, and DRS.
  • Main Results:

    • A single face-centered cubic (fcc) spinel structure (Fd-3m space group) was confirmed.
    • Crystallite size increased from 4.54 to 102.54 nm with rising sintering temperature.
    • Superparamagnetic behavior was observed at smaller sizes (4.54-5.10 nm), transitioning to ferrimagnetic at larger sizes.
    • Saturation magnetization increased from 9.49 to 33.04 emu/g with enhanced crystallite size.
    • Optical band gap was determined to be in the range of 1.84-2.26 eV, indicating semiconducting properties.
    • The material showed potential for photocatalytic O2 generation.

    Conclusions:

    • Sintering temperature is a critical parameter for tuning the properties of Cu-Mg nanoferrites.
    • The prepared nanoferrites exhibit tunable magnetic properties and semiconducting characteristics.
    • Cu-Mg nanoferrites demonstrate promise as efficient photocatalysts for solar energy applications.
    Structural