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Updated: Jun 4, 2025

Sample Preparation for Probe Electrospray Ionization Mass Spectrometry
Published on: February 19, 2020
Preparation of a 73As source sample for application in an offline ion source
Andrew C Candia1, Georg Bollen2, Suvan Campbell3
1Facility for Rare Isotope Beams, Michigan State University, 640 South Shaw Lane, East Lansing, 48824, MI, USA; Department of Chemistry, Michigan State University, 640 South Shaw Lane, East Lansing, 48824, MI, USA.
Abstract:
For the generation of beams with the offline ion source at the Facility for Rare Isotope Beams (FRIB), suitable source samples are required. Arsenic-73 is a frequently requested user beam due to its significance in nuclear structure studies and astrophysics. In this work, we outline the process of preparing a 73As source sample, containing (5.76 ± 0.37)∗1014 atoms of 73As, which was successfully used to generate a 73As beam for a multi-day user experiment. Silver arsenate was chosen as the chemical form, due to its favorable volatility within the designated operating temperature range. We refined the precipitation method using stable arsenic prior to its application with the 73As sample, resulting in precipitation yields of (99.4 ± 4.5)%.
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