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Updated: Jun 4, 2025
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
Organometallic Photocatalyst-Promoted Synthesis and Modification of Carbohydrates under Photoirradiation
Abstract:
Carbohydrates are natural, renewable, chemical compounds that play crucial roles in biological systems. Thus, efficient and stereoselective glycosylation is an urgent task for the preparation of pure and structurally well-defined carbohydrates. Photoredox catalysis has emerged as a powerful tool in carbohydrate chemistry, providing an alternative for addressing some of the challenges of glycochemistry. Over the last few decades, Ir- and Ru-based organometallic photocatalysts have attracted significant interest because of their high stability, high-energy triplet state, strong visible-light absorption, long luminescence lifetime, and amenability to ligand modification. This review highlights the recent progress in the organometallic photocatalyst-promoted synthesis and modification of carbohydrates under photoirradiation, as well as the related benefits and drawbacks.
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