Controlled growth of silver on gold triangular nanoprisms: Improved surface enhanced Raman scattering for...

The precise design and synthesis of Au and Ag composite nanomaterials can provide them with richer plasmonic modes, resulting in enhanced optical properties. Here, a novel strategy was demonstrated to control the selective deposition of Ag at different positions of Au triangular nanoprisms (Au TNPs). 1,4-benzenedithiol (BDT) was selectively absorbed in different positions of Au TNPs which made Ag selectively deposited on Au TNPs. A series of Ag islands-Au TNPs including 3AgNPs islands-Au@Ag TNPs, 3AgNPs islands-Au TNPs, 2AgNPs islands-Au TNPs and 1AgNPs island-Au TNPs were obtained. We found that Surface enhanced Raman scattering (SERS) activity was closely associated with the position of Ag deposition under the same volume of AgNO₃. It has strongest SERS activity when Ag deposit on the surface, edges and corners of Au TNPs which corresponding to 3AgNPs islands-Au@Ag TNPs with a high enhancement factor of 5.50 × 10⁷. Raman reporter molecules were embedded between Au core, Ag shell and Ag islands which enhanced the stability, making them ideal candidates for Raman tag-based applications. We used it as SERS probes to realize the ultra-sensitive detection of Cyfra21-1, with a low limit of detection of 2.84 × 10^-14 g/L and a wide linear range of 1.00 × 10^-13-1.00 × 10^-1 g/L.