Advanced Catalysts for the Chemical Recycling of Plastic Waste

Plastic products bring convenience to various aspects of the daily lives due to their lightweight, durability and versatility, but the massive accumulation of post-consumer plastic waste is posing significant environmental challenges. Catalytic methods can effectively convert plastic waste into value-added feedstocks, with catalysts playing an important role in regulating the yield and selectivity of products. This review explores the latest advancements in advanced catalysts applied in thermal catalysis, microwave-assisted catalysis, photocatalysis, electrocatalysis, and enzymatic catalysis reaction systems for the chemical recycling of plastic waste into valuable feedstocks. Specifically, the pathways and mechanisms involved in the plastics recycling process are analyzed and presented, and the strengths and weaknesses of various catalysts employed across different reaction systems are described. In addition, the structure-function relationship of these catalysts is discussed. Herein, it is provided insights into the design of novel catalysts applied for the chemical recycling of plastic waste and outline challenges and future opportunities in terms of developing advanced catalysts to tackle the "white pollution" crisis.