Coordination Equilibrium-Assisted Coprecipitation Synthesis of Atomically Dispersed 3d Metal Catalysts

As a frontier of heterogeneous catalysis, single-atom catalysts (SACs) have been extensively studied fundamentally. One obstacle that limits the industrial application of SACs is the lack of a synthetic method that can prepare the catalysts on a large scale. Wet-chemistry methods that are conventionally used to prepare nanoparticle-based industrial catalysts might be a solution. In this work, we report a coprecipitation method using ethylenediaminetetraacetic acid (EDTA) as an equilibrium regulator to synthesize a series of atomically dispersed 3d metal over the Mg(OH)₂ support. Mg(OH)₂ is formed from the spontaneous dissolution of MgO, which is also the alkali source for coprecipitation to occur. The dissolution-precipitation equilibria of metal hydroxides compete with the coordination equilibria of EDTA-coordinated metal cations, leading to the coprecipitation of loaded metal and Mg²⁺ cations. The synthetic strategy is applicable for Fe, Co, Ni, and Cu, forming four catalysts that are active for the photodegradation of methylene blue under visible light.