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Physical, Chemical and Biological Characterization of Six Biochars Produced for the Remediation of Contaminated Sites
Published on: November 28, 2014
Optimizing biochar-based column filtration systems for enhanced pollutant removal in wastewater treatment: A
Sofiane El Barkaoui1, Laila Mandi2, Michelangelo Fichera3
1Laboratory of Water, Biodiversity and Climate Change (EauBiodiCc), Faculty of Sciences Semlalia, University Cadi Ayyad, Marrakech, Morocco; National Centre for Studies and Research on Water and Energy (CNEREE), University Cadi Ayyad, Marrakech, Morocco; Department of Chemistry, University of Florence, Via Della Lastruccia, 3, Sesto Fiorentino, 50019, Florence, Italy.
Abstract:
This study aims to test the efficiency of biochar-based substrates in removing chemical and bacteriological pollutants from wastewater and to determine the optimal percentage of biochar (BC) to implement for large-scale filters (e.g., constructed wetlands). So, a preliminary test was conducted on a lab column scale for wastewater treatment of decanted wastewater using column filtration systems (CFS) integrated with BC (BC-based CFSs) at different concentrations (0%, 10%, 25%, and 50%). The BC used here was produced from exhausted olive pomace (pyrolised at T 590 °C, residence time of 2 h and a heating rate of 10 °C min-1). The results revealed that the BC incorporated into the CFS improved the efficiency of nitrogen species removal (total nitrogen (TN) 64-65%, total kjeldahl nitrogen (TKN) 75%-77%, organic nitrogen (ON) 78%-87%, and NH4+-N 57%-69%); phosphorus species (total phosphorus (TP) 39%-44%, PO43- 38%-42%); total and soluble chemical oxygen demand (TCOD (44%-56%), and SCOD (33%-51%) respectively); and total suspended solids (TSS) 87%-92%, compared to the control filter (CFS0). Bacteriological analysis focused on faecal bacteria indicators, including total coliforms (TC), faecal coliforms (FC), faecal streptococci (FS), as well as the pathogen Staphylococcus (SP) and total aerobic mesophilic flora (TAMF). The highest removal efficiencies were observed for CFS10. Based on this preliminary study, the efficiency of CFS in removing pollutants from wastewater is optimal with a small amount of BC (10%) from both water quality and economic points of view.
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