Pseudotunnel Magnetoresistance in Twisted van der Waals Fe₃GeTe₂ Homojunctions

Twistronics, a novel engineering approach involving the alignment of van der Waals (vdW) integrated two-dimensional materials at specific angles, has recently attracted significant attention. Novel nontrivial phenomena have been demonstrated in twisted vdW junctions (the so-called magic angle), such as unconventional superconductivity, topological phases, and magnetism. However, there have been only few reports on integrated vdW layers with large twist angles θ_t, such as twisted interfacial Josephson junctions using high-temperature superconductors. Herein, vdW homojunctions of the thin-magnetic flakes, Fe₃GeTe₂ (FGT), with large θ_t ranging from 0° to 90°, without inserting any tunnel barriers are assembled. Nevertheless, these vdW homojunctions exhibit tunnel-magnetoresistance (TMR) like behavior (pseudo-TMR (PTMR) effect) with the ratios highly sensitive to the θ_t values, revealing that the vdW gap at the junction interface between the twisted FGT layers behaves like a tunnel barrier and the θ_t serves a control parameter for PTMR by drastically varying magnitudes of the lattice-mismatch and the subsequent appearance of antiferromagnetic (AFM) spin alignment. First-principles calculations considering vacuum gaps indicate strong dependence of TMR on the θ_t driven by the sixfold screw rotational symmetry of bulk FGT. The present homojunctions hold promise as a platform for novel AFM spin-dependent phenomena and spintronic applications.