Oxidative Polymerization in Water Treatment: Chemical Fundamentals and Future Perspectives

For several decades, the methodology of complete destruction of organic pollutants via oxidation, i.e., mineralization, has been rooted in real water treatment applications. Nevertheless, this industrially accepted protocol is far from sustainable because of the excessive input of chemicals and/or energy as well as the unregulated carbon emission. Recently, there have been emerging studies on the removal of organic pollutants via a completely different pathway, i.e., polymerization, meaning that the target pollutants undergo oxidative polymerization reactions to generate polymeric products. These studies have collectively shown that compared to the conventional mineralization pathway, the polymerization pathway allows more efficient removal of target pollutants, largely reduced input of chemicals, and suppressed carbon emission. In this review, we aim to provide a comprehensive examination of the fundamentals of the oxidative polymerization process, current state-of-the-art strategies for regulation of the polymerization pathway from both kinetic and thermodynamic perspectives, and resource recovery of the formed polymeric products. In the end, the limitations of the polymerization process for pollutant removal are discussed, with perspectives for future studies. Hopefully, this review could not only provide critical insight for the advancement of polymerization-oriented technologies for removal of more organic pollutants in a greener manner but also stimulate more paradigm innovations for low-carbon water treatment.