Assessment of the Variability in the Occurrence of PFAS in Fish Tissues from Selected Fisheries in the Baltic Sea

In this study, the results of a comprehensive assessment of the variability in the occurrence of ten perfluorinated compounds (PFAS) in fish tissues originating from 2014 to 2019 from six fisheries in the Baltic Sea are presented. A total of 360 fish samples of three species (perch, herring and flatfish) were analysed. For the determination of PFAS, both linear and branched stereoisomers, LC-ESI-MS/MS technique preceded by simultaneous SPE isolation was validated and applied. The total concentration of all determined PFAS compounds shows that the highest levels were observed in the Szczecin Lagoon (4.8 ± 0.7 µg/kg) and the lowest in the Pomeranian Bay (1.9 ± 0.1 µg/kg). In most samples, the dominant compound was perfluorooctane sulfonic acid (PFOS). The present research enabled the assessment of the variability in the occurrence of PFAS stereoisomers in marine fish.