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First wheat certified reference material for organically bound tritium measurement in the environment
Marielle Crozet1, Audrey Bacchetta2, Nicolas Baglan3
1CEA, DES, ISEC, DMRC, CETAMA, Univ. Montpellier, Marcoule, France.
Talanta
|January 12, 2025
Summary
Accurate measurement of organically bound tritium (OBT) in environmental samples is challenging. This study introduces the first certified reference material to improve the trueness of OBT radioactivity measurements.
Area of Science:
- Environmental Science
- Radiochemistry
- Analytical Chemistry
Background:
- Measuring organically bound tritium (OBT) radioactivity in environmental samples presents significant analytical challenges.
- Numerous laboratories have focused on developing reliable OBT measurement techniques over the past two decades.
- Interlaboratory comparisons have been conducted to refine these methods, but a lack of certified reference materials has hindered the assessment of measurement trueness.
Purpose of the Study:
- To address the need for accurate OBT quantification in environmental matrices.
- To present the development and production of the first certified reference material (CRM) for OBT radioactivity.
- To enable laboratories to validate and improve the trueness of their OBT measurement methods.
Main Methods:
- Production of a certified reference material specifically for organically bound tritium.
- Characterization of the OBT content in the reference material.
- Establishment of traceability for radioactivity measurements.
Main Results:
- Successful production of the first certified reference material for organically bound tritium radioactivity in environmental samples.
- The CRM provides a benchmark for assessing the trueness of OBT measurement methods.
- This material facilitates interlaboratory comparisons and method validation.
Conclusions:
- The availability of this OBT certified reference material is a significant advancement for environmental radioactivity monitoring.
- It will enhance the reliability and comparability of OBT measurements across different laboratories.
- This CRM is crucial for accurate environmental risk assessment and regulatory compliance.

