Mechanism, Performance, and Application of g-C₃N₅-Coupled TiO₂ as an S-Scheme Heterojunction Photocatalyst for the...

In this research, S-scheme heterojunction photocatalysts are prepared through the hybridization of nitrogen-rich g-C₃N₅ with TiO₂ (coded as TCN₅-(x): x as the weight ratio of TiO₂:g-C₃N₅). The photocatalytic potential of TCN₅-(x) is evaluated against benzene (1-5 ppm) across varying humidity levels using a dynamic flow packed-bed photocatalytic reactor. Among the prepared composites, TCN₅-(10) exhibits the highest synergy between g-C₃N₅ and TiO₂ at "x" ratio of 10%, showing superior best benzene degradation performance (e.g., 93.9% removal efficiency, specific clean air delivery rate of 1126.9 L g^-1 h^-1, kinetic reaction rate of 46.1 nmol mg^-1 min^-1, quantum yield of 6.0 × 10^-4 molec. photon^-1, and space-time yield of 1.2 × 10^-4 molec. photon^-1 mg^-1). The formation of an S-scheme heterojunction with a built-in internal electric field is supported by both theoretical (through the density functional theory calculations) and photoelectrochemical bases (e.g., improvement in the band potential and electrochemistry along with surface characteristics (e.g., reactive sites and charge migrations at the interface)). The results of the in situ DRIFTS analysis confirm that the oxidation of benzene molecules is accompanied by many reaction intermediates (e.g., phenolate, maleate, acetate, and methylene). The outcomes of this work will help us pursue the development of a state-of-the-art photocatalytic system for air quality management.