Related Experiment Video
Updated: Jun 3, 2025

Designed for Molecular Recycling: A Lignin-Derived Semi-aromatic Biobased Polymer
Published on: November 30, 2020
Biobased vitrimers: towards sustainability and circularity
Alberto Mariani1, Giulio Malucelli2
1Department of Chemical, Physical, Mathematical and Natural Sciences, University of Sassari, Via Vienna 2, 07100 Sassari, Italy.
Biobased vitrimers, materials with adaptable covalent networks, offer sustainable alternatives to traditional plastics. This review highlights their advanced applications, promoting circular economy principles and reducing environmental impact.
Area of Science:
- Polymer Science and Technology
- Materials Science
- Sustainable Chemistry
Background:
- Traditional polymers are classified as thermoplastics (reprocessable) or thermosets (irreversible cross-linked networks).
- Vitrimers, discovered in 2011, are a distinct class of materials featuring covalent adaptable networks (CANs).
- CANs enable topology changes via thermally activated bond-exchange reactions, bridging the gap between thermoplastics and thermosets.
Purpose of the Study:
- To review the current applications of biobased vitrimers in advanced material design.
- To emphasize the significance of biobased vitrimers in achieving green and sustainable material solutions.
- To align the use of these materials with the principles of the circular economy.
Main Methods:
- Literature review of existing research on biobased vitrimers.
- Analysis of synthesis and characterization studies.
- Evaluation of advanced applications and their alignment with sustainability goals.
Main Results:
- Biobased vitrimers offer a sustainable alternative to fossil-based polymers.
- They exhibit reduced environmental impact compared to traditional materials.
- Existing chemistries and production platforms can be adapted for biobased vitrimer synthesis.
Conclusions:
- Biobased vitrimers are crucial for developing novel, eco-friendly materials.
- Their unique properties support the transition towards a circular economy.
- These materials represent a practical approach to enhancing the sustainability of polymer technologies.
Related Concept Videos
Environmental Applications of Microorganisms
What are Biogeochemical Cycles?
Bioremediation
Microorganisms in Agriculture and Food industry
Types of Step-Growth Polymers: Polyesters
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...

