Facile preparation of marine carrageenan hydrogel-coated steel mesh with superhydrophilic and underwater superoleophobic performance for highly efficient oil-water separation

  • 0Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control, Zhejiang Ocean University, Zhoushan, P. R. China.

Summary

This summary is machine-generated.

A novel biomimetic membrane from marine algae efficiently separates oil from water. This superhydrophilic, underwater superoleophobic material offers a reusable, eco-friendly solution for wastewater treatment with high oil-water separation efficiency.

Area Of Science

  • Materials Science
  • Environmental Science
  • Chemical Engineering

Background

  • Industrial wastewater and oil spills threaten ecosystems and health.
  • Special wettability membranes offer efficient oil-water separation.
  • Biomimetic superhydrophilic-underwater superoleophobic membranes are promising.

Purpose Of The Study

  • To develop a novel membrane for efficient oil-water separation.
  • To utilize a biocompatible and renewable hydrogel from marine red algae.
  • To create a membrane inspired by biomimetic fish scales.

Main Methods

  • Fabricated a membrane using a stainless steel mesh coated with carrageenan hydrogel.
  • Utilized sodium periodate as a crosslinking agent for in-situ gelation.
  • Characterized membrane properties including wettability, separation efficiency, and stability.

Main Results

  • Achieved superhydrophilicity and underwater superoleophobicity (oil contact angle ≥ 158°).
  • Demonstrated high separation efficiencies for various oils (97.98%–98.87%) and high water flux (1380.75 L/m²·h).
  • Maintained efficiency over 20 cycles and showed stability in alkaline conditions.

Conclusions

  • The carrageenan-based membrane is effective for oil-water separation.
  • The biomimetic design offers excellent antifouling and self-cleaning properties.
  • This renewable material is suitable for treating complex oily wastewater.