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Updated: Jun 2, 2025

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Ligand labilization gates intramolecular electron transfer in molecular photocatalyst
Louis Blechschmidt1,2, Linda Zedler1,2, Alexander K Mengele3
1Institute of Physical Chemistry, Friedrich Schiller University Jena, Helmholtzweg 4, 07743 Jena, Germany.
Abstract:
Identification of rate determining steps concerning catalyst activation and catalytic turnover is key to optimize molecular photocatalysts. In this contribution, femtosecond transient absorption spectroscopy upon variation of temperature and ionic strength yields new insights into the light-driven reactivity of the benchmark molecular photocatalyst, RutpphzRhCp*.
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