Localized Nanoscale Formation of Vanadyl Porphyrin 2D MOF Nanosheets and Their Optimal Coupling to Lumped Element...

A strategy toward the realization of a quantum spin processor involves the coupling of spin qubits and qudits to photons within superconducting resonators. To enable the realization of such hybrid architecture, here we first explore the design of a chip with multiple lumped-element LC superconducting resonators optimized for their coupling to distinct transitions of a vanadyl porphyrin electronuclear qudit. The controlled integration of the vanadyl qudit onto the superconducting device, both in terms of number and orientation, is then attained using the in situ formation of nanosheets of a 2D framework built on the vanadyl qudit as a node. Low-temperature transmission experiments demonstrate the coupling of photons in resonators with different frequencies to the targeted electronuclear transitions of the vanadyl qudit, also confirming the control over the vanadyl qudit node orientation. The derived collective spin-photon couplings in the 0.3-1.6 MHz range then allow to estimate enhanced, optimal, single spin photon couplings up to 4 Hz.