Soft nanoforest of metal single atoms for free diffusion catalysis

Metal single atoms are of increasing importance in catalytic reactions. However, the mass diffusion is yet substantially limited by the confined surface of the support in comparison to homogeneous catalysis. Here, we demonstrate that cylindrical micellar brushes with highly solvated poly(2-vinylpyridine) coronas can immobilize 33 types of metal single atoms with 8.3 to 40.9 weight % contents on conventional electrodes under ambient conditions. This is favored by the forest-like hierarchically open soft structure of the micellar brushes and the dynamic coordination between the metals and the pyridine groups. It was found that the nanoforests of individual noble metal single atoms can be well solvated in an aqueous electrolyte to comprehensively expose the atomic active sites and the nanoforest of Pt single atoms on nickel foam reveals high electrochemical performance for hydrogen evolution. The micellar brush support also enables the simultaneous anchoring of multiple single atoms on the cathode of an anion-exchange membrane electrolyzer for long-term stable water electrolysis.