Lignin reinforced eco-friendly and functional nanoarchitectonics materials with tailored interfacial barrier...

Exploring innovative and sustainable routes for the production of biodegradable biomass-based materials is critical to promote a circular carbon economy and carbon neutrality goals. Fossil-based non-biodegradable plastic waste poses a nonnegligible threat to humans and the ecological environment, and biomass-based functional materials are becoming increasingly viable alternatives. Lignin, a naturally occurring macromolecular polymer, is green and renewable resource rich in aromatic rings, with biodegradability, biocompatibility, and excellent processability for eco-friendly composites. Moreover, versatile and high tunable lignins can be valorized into functional materials, which are crucial building blocks in the fabrication of biomass-derived composites. Lignin's unique chemical structure, solvent resistance, anti-aging, and anti-ultraviolet functional properties make it highly potential for the fabrication of sustainable biobased barrier materials. This review systematically summarizes the progress in the fabrication and application of lignin-based functional composites, with a particular focus on barrier materials. First, the structural diversity of lignins from different sources and fractionation methods, and the structural modification strategies of lignins are briefly introduced. Then, the multiple barrier performances of lignin-based composites are listed, and the fabrication methods of different composites based on the polymer matrix systems are elaborated. In terms of diverse applications, this review highlights the multifaceted barrier properties of lignin-based composites in oxygen barrier, water vapor barrier, ultraviolet barrier, flame retardant and antibacterial applications. These functional barrier materials are widely used in food/pharmaceutical packaging, agricultural protection, construction, etc., providing an excellent option for sustainable materials with high barrier performance requirements. Finally, the main challenges faced by lignin-based barrier materials and the future directions are proposed.