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Updated: Jun 1, 2025
![Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F55858.jpg&w=3840&q=50)
Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
Published on: December 4, 2017
H2O2 Mediated Photoreduction of Nitrates to Ammonia by Iron Filings under Ambient Conditions
Anjali Kumari Garg1, Vishrant Kumar1,2, Rohit1
1Department of Chemistry, Malaviya National Institute of Technology, Jaipur, Jaipur 302017, India.
Abstract:
Herein, a simple ambient conditioned sunlight promoted photochemical reduction reaction is demonstrated for the of nitrate (NO3-) conversion to ammonia (NH3) with the maximum conversion yield of ∼16 mM using iron filings (f-Fe) in the presence of H2O2. Based on a radical scavenging study of reactive species and the characterization of catalyst f-Fe before and after the reaction, a plausible mechanism has been proposed for the ambient conditioned synthesis of NH3. The results associated with the NH3 synthesis have been verified using the 15N isotopic labeled nitrate (15NO3-), which supports the simpler viability of the reported procedure.
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