Influence of 1-Hexanol/Waste Plastic Oil Blends on Combustion, Performance, and Emission Characteristics of a Common Rail Direct Injection Diesel Engine

  • 0School of Mechanical Engineering, VIT-AP University, Amaravati, Andhra Pradesh 522237, India.

|

Summary

This summary is machine-generated.

Related Concept Videos

Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes 02:14

6.2K

The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were  initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...

Electrophilic Addition of HX to 1,3-Butadiene: Thermodynamic vs Kinetic Control 01:23

2.5K

The addition of a hydrogen halide to 1,3-butadiene gives a mixture of 1,2- and 1,4-adducts. Since more substituted alkenes are more stable, the 1,4-adduct is expected to be the major product. However, the product distribution is strongly influenced by temperature; low temperature favors the 1,2-adduct, whereas the 1,4-adduct is predominant at high temperature.

At lower temperatures, the two products are not in equilibrium. Under these conditions, the product distribution depends on the...

Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism 01:18

2.2K

Birch reduction uses solvated electrons as reducing agents. The reaction converts benzene to 1,4-cyclohexadiene. The reaction proceeds by the transfer of a single electron to the ring to form a benzene radical anion. This anion is highly basic—it abstracts a proton from the alcohol to form a cyclohexadienyl radical. Another single electron transfer gives the cyclohexadienyl anion. A proton transfer from the alcohol forms 1,4-cyclohexadiene. Since this reduction occurs via radical anion...

Electrophilic 1,2- and 1,4-Addition of HX to 1,3-Butadiene 01:17

5.3K

The electrophilic addition of hydrogen halides such as HBr to alkenes and nonconjugated dienes gives a single product as per Markovnikov’s rule.

With conjugated systems like 1,3-butadiene, the addition of one equivalent of HBr yields a mixture of products: 1,2 and 1,4-addition products. As shown below, the mechanism involves the addition of H+ across one of the double bonds of the conjugated diene to form a resonance stabilized allyl cation. This is followed by the nucleophilic attack of...