Heterointerface Built Up by Ultrathin Amorphous MoO₃ Conformal Coating Enables V₅O₁₂·6H₂O with Superior Properties...

Layered V₅O₁₂·6H₂O is a promising candidate for aqueous zinc batteries (AZBs) but with moderate electrochemical performances. Herein, the charge storage properties of V₅O₁₂·6H₂O are markedly improved by building up the heterointerface on its surface using amorphous molybdenum trioxide as the heteromaterial. The amorphous molybdenum trioxide functioning as the proton reservoir enables the proton-involved electrochemical reactions and induces the formation of a built-in electric field along the [001] orientation at the heterointerface constructed by the (001) plane of V₅O₁₂·6H₂O, which could provide new diffusion pathways and extra sites for ion storage. As a result, V₅O₁₂·6H₂O with significantly improved kinetics realizes an ultrahigh capacity of 510 mAh g^-1, better rate capability, and prolonged lifespan. This work provides general guidance for designing advanced cathode materials for AZBs with respect to heterostructure.