A vinylene-linked diketopyrrolopyrrole-based covalent organic framework for photocatalytic oxidation reactions
Wei Zhao1, Jing-Lan Kan1, Chaowei Zhao2
1College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China. yangfan1180@sdnu.edu.cn.
Abstract:
A vinylene-linked DPP-COF with an ultra-narrow bandgap of 1.06 eV was reported. This COF demonstrates high chemical stability and significant charge transfer properties, and was applied to the photooxidation of sulfides and tetrahydroisoquinolines, exhibiting exceptional photoactivities.
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