Related Experiment Video
Updated: May 31, 2025

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Applications of Verdazyl Radicals in Energy Storage, Molecular Electronics and Magnetism: Teaching Old Molecules New
Margot Duggin1, Alex C Bissember1, Rebecca O Fuller1
1School of Natural Sciences - Chemistry, University of Tasmania, Hobart, Tasmania, 7001, Australia.
Abstract:
Verdazyls are a fundamental class of stable organic radicals that have been traditionally overshadowed by the more synthetically accessible stable nitroxide radicals. With the advent of enhanced synthetic routes to verdazyls, particularly in recent years, these systems are now poised to realise their potential in a range of applications across emerging technologies that will be important to addressing challenges faced by modern society. This review discusses the enabling properties of a selection of verdazyl-based systems that feature promising applications in energy storage, molecular electronics and magnetic molecules. Emphasis is placed on progress in these areas over the past ~5 years.
Related Concept Videos
Radical Reactivity: Overview
Radical Formation: Addition
Similar to charge conservation in chemical reactions, spin conservation is implicit for radical reactions. Accordingly, the product formed must possess an...
Radical Formation: Overview
Radicals from spin-paired molecules:
Radicals can be obtained from spin-paired molecules either by homolysis or electron transfer. While two radicals are formed in the former, an electron is added in the...
Radical Reactivity: Steric Effects
Along with electronic...
Radical Formation: Abstraction
Even though homolysis produces radicals, it is different from radical...
Electron Paramagnetic Resonance (EPR) Spectroscopy: Organic Radicals

