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Updated: May 31, 2025

Preparation of N-2-alkoxyvinylsulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
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Benzo-Fused Phosphepines: Synthesis by Gold(I)-Catalyzed Intramolecular Hydroarylation and Ring Inversion

Akihiro Tsurusaki1, Marii Kishimoto1, Akihiro Komura1

  • 1Department of Chemistry, Graduate School of Science, Osaka Metropolitan University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka, 558-8585, Japan.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|January 24, 2025
PubMed
Summary

Gold(I) catalysis enables the synthesis of benzo-fused phosphepine oxides. Diastereomeric O-exo and O-endo adducts form, with their interconversion influenced by substituents and ring fusion.

Keywords:
gold(I) catalysthydroarylationphosphepinering inversiontheoretical calculation

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