Electrochemical reduction for chlorinated hydrocarbons contaminated groundwater remediation: Mechanisms, challenges,...

Electrochemical reduction technology is a promising method for addressing the persistent contamination of groundwater by chlorinated hydrocarbons. Current research shows that electrochemical reductive dechlorination primarily relies on direct electron transfer (DET) and active hydrogen (H^⁎) mediated indirect electron transfer processes, thereby achieving efficient dechlorination and detoxification. This paper explores the influence of the molecular charge structure of chlorinated hydrocarbons, including chlorolefin, chloroalkanes, chlorinated aromatic hydrocarbons, and chloro-carboxylic acid, on reductive dechlorination from the perspective of molecular electrostatic potential and local electron affinity. It reveals the affinity characteristics of chlorinated hydrocarbon pollutants, the active dechlorination sites, and the roles of substituent groups. It also comprehensively discusses the current progress on electrochemical reductive dechlorination using metal, carbon-based, and 3D electrode catalysts, with an emphasis on the design and optimization of electrode materials and the impact of catalyst microstructure regulation on dechlorination performance. It delves into the current application status of coupling electrochemical reduction technology with biodegradation and electrochemical circulating well technology for the remediation of groundwater contaminated by chlorinated hydrocarbons. The paper discusses practical application challenges such as electron transfer, electrode corrosion, water chemistry environment, and aquifer heterogeneity. Finally, considerations are presented from the perspectives of environmental impact and sustainable application, along with a summary and analysis of potential future research directions and technological prospects.