Study on Synergistically Improving Corrosion Resistance of Microarc Oxidation Coating on Magnesium Alloy by Loading
Ziyi Wang1, Lingyun An1, Chenggong Chang2,3
1Qinghai Provincial Key Laboratory of Nanomaterials and Technology, School of Chemistry and Materials Science, Qinghai Minzu University, Xining 810007, China.
Abstract:
Sodium tungstate (Na2WO4) was filled into the micropores and onto the surface of a magnesium alloy microarc oxidation (MAO) coating by means of vacuum impregnation. Subsequently, the coating was sealed through silane treatment to synergistically boost its corrosion resistance. The phase composition of the coating was inspected using XRD. FTIR was utilized to analyze the functional groups in the coating. XPS was employed to study the chemical composition and valence state of the coating. The surface and cross-sectional morphology of the coating, along with its elemental composition and distribution, were investigated by SEM and EDS. Meanwhile, the thickness of the coating was analyzed using Image J software. Electrochemical impedance spectroscopy (EIS) was employed to determine the corrosion resistance of the coating. The results show that compared with an MAO coating, M-0.125W composite coating (only filled with sodium tungstate on the surface of the MAO coating), and M-SG composite coating (only receiving silanization treatment applied to the surface of the MAO coating), the corrosion resistance of the M-nW-SG composite coating (loaded with sodium tungstate on the surface of the MAO coating and then treated with silane) is significantly improved. This is mainly attributed to the fact that sodium tungstate can be combined with Mg2+ to form insoluble magnesium tungstate protective film, which blocks corrosion media. At the same time, silanization treatment further seals the MAO coating and increases the compactness of the coating. In addition, with the increase in the impregnation concentration of sodium tungstate, the content of sodium tungstate in the M-nW-SG composite coating improves, and the sealing effect of silanization treatment is better. When the impregnation concentration of sodium tungstate is 0.1 mol/L or above, the MAO coating with sodium tungstate can be completely sealed. When the impregnation concentration of sodium tungstate is 0.125 mol/L, M-0.125W-SG composite coating has the best corrosion resistance, and its impedance modulus value can be maintained at 8.06 × 106 Ω·cm2 after soaking in 3.5 wt.% NaCl solution for 144 h, which is about three orders of magnitude higher than those of MAO coating and M-0.125W and M-SG composite coatings.
