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KOBu-Promoted [3 + 2] Cycloaddition of Dimethyl Sulfoxide with Fullerenes
Fei Li1, Jin-Ying Liu1, Bin-Wen Chen2
1Anhui Province Key Laboratory of Structure and Functional Regulation of Hybrid Materials, Department of Chemistry, College of Chemistry and Chemical Engineering, Anhui University, Hefei, Anhui 230601, People's Republic of China.
Abstract:
KOBu-promoted [3 + 2] cycloaddition of dimethyl sulfoxide (DMSO) with fullerenes has been developed for facile and efficient one-pot synthesis of 1,2,3,4-cyclic sulfoxide-fused [60]/[70]fullerene dihydrides, which offers a versatile platform for the site-selective preparation of various fullerene multiadducts with a wide range of functional groups. The utility of these tetra-functionalized fullerenes is demonstrated by the successful application as electron-transport materials in perovskite solar cells.
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