Related Experiment Video
Updated: May 30, 2025
Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Fe3O4@HA-Cu(OAc)2 nanocomposite as a nanomagnetic water-compatible catalyst for efficient synthesis of
Beheshteh Arjmandzadeh1, Abbas Ali Jafari2
1Department of Chemistry, Yazd University, Yazd, Iran.
Abstract:
A new humic acid-based nanomagnetic copper(II) composite was prepared and used as an eco-friendly recoverable catalyst for synthesizing 1,4-disubstituted 1,2,3-triazoles. The synthesis was done via the three-component click reaction of alkyl halide, sodium azide, and terminal alkyne with good to excellent yield. A simple magnetic copper acetate composite, Fe3O4@HA-Cu(OAc)2, was prepared using humic acid and characterized by SEM, TEM, XRD, EDX, EDS-mapping, VSM, TGA, AAS, and FT-IR. The catalyst showed high catalytic potential in a one-pot three-component click reaction in the synthesis of 1,2,3-triazoles. The nanomagnetic Fe3O4@HA-Cu(OAc)2 catalyst demonstrated high efficiency, stability, compatibility with oxygen/water and recyclable copper(II), with cost-effectiveness. The catalyst was easily recovered with an external magnetic field, and therefore, time and energy were saved as no filtration or decantation technique was needed. Due to the high dispersibility in water, nanomagnetic Fe3O4@HA-Cu(OAc)2 was utilized as a highly efficient catalyst for the click synthesis of triazoles.
More Related Videos
08:40Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
08:12Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
Published on: September 5, 2018