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Updated: May 5, 2026

Layer-by-layer Synthesis and Transfer of Freestanding Conjugated Microporous Polymer Nanomembranes
Published on: December 15, 2015
Exploring chiral and achiral properties of novel multilayer 3D polymers: synthesis and characterization
Sai Zhang1, Qingzheng Xu2, Xiuyuan Qin3
1School of Pharmacy, Continuous Flow Engineering Laboratory of National Petroleum and Chemical Industry, Changzhou University Changzhou Jiangsu Province 213164 China.
Abstract:
This study reports the novel synthesis of multilayered 3D polymers via the 1,3,5-position coupling of 1,3,5-tris(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene with 1,8-dibronaphthalene, a previously unreported method. The resulting polymers exhibit both achiral and chiral characteristics, offering a unique platform for structural and functional exploration. Comprehensive characterization using gel permeation chromatography, UV-vis spectroscopy, fluorescence measurements, circular dichroism, and scanning electron microscopy revealed intriguing optical properties and morphological features, promoting potential applications in photonics, sensors, and materials science.
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