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Updated: May 29, 2025

Preparation of N-2-alkoxyvinylsulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
Published on: January 3, 2018
Radical 1,3-Hydrosulfonylation of Vinyldiazo Compounds with Sulfinyl Sulfones
Jing Tian1, Yuanli Ding2, Wanting Fu1
1College of Chemistry and Materials Science, Hebei University, Baoding 071002, China.
Abstract:
Sulfinyl sulfones, as high-valence sulfurization reagents, are widely used to assemble sulfur sources on carbon skeletons, such as one-, two-, and four-carbon synthons, to access organosulfur compounds. However, their reaction with three-carbon synthons has remained a mystery until now. We report here a radical 1,3-hydrosulfonylation of vinyldiazo compounds with sulfinyl sulfones. This reaction not only represents the first example of the reaction of sulfinyl sulfones with three-carbon synthons but also opens up the application of vinyldiazo compounds in radical monofunctionalization.
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