Optoelectric coordinated modulation of resistive switching behavior in perovskite based synaptic device

Triple cation halide perovskite (TCP) stands out as a superior photoelectric material, with a broader absorption range, higher absorption efficiency, and improved environmental stability. Due to its excellent synaptic plasticity, TCP facilitates advanced neural morphological operations like light-assisted learning. Here, a modifying layer of polythiophene (P3HT) was incorporated onto the TCP thin film to enhance the resistive switching (RS) characteristics of the synaptic device, which exhibits excellent stability (10³ endurance cycles and > 10³ s retention time) and low energy consumption (~ 6.3 pJ for electrical stimulus and ~ 6 pJ for optical stimulus). Additionally, the synaptic properties of the perovskite / P3HT heterojunction synaptic device were explored under optoelectric coordinated modulation, encompassing Long-Term Potentiation (LTP), Long-Term Depression (LTD), frequency-dependent plasticity (SRDP) and voltage-dependent plasticity (SVDP). By leveraging the linear characteristics of synaptic plasticity, arithmetic operations, Pavlovian conditioned reflex and vision recognition are achieved. The recognition accuracies of 89.8% / 88.1% (electric synapse) are enhanced to 92.4% / 92.2% after the introduction of optoelectronic cooperative stimulation on the 8 × 8 and 28 × 28 modified national institute of standards and technology (MNIST) handwritten digit datasets. This study holds significant implications for guiding the optoelectronic co-regulation of perovskite synaptic devices in the field of synaptic electronics.