Biochar for mitigating pharmaceutical pollution in wastewater: A sustainable solution

Pharmaceutical contaminants (PCs), including antibiotics, analgesics, and other medications, pose a growing threat to aquatic ecosystems and human health due to their persistence and bioaccumulation potential. Biochar, a carbonaceous material derived from biomass pyrolysis, has emerged as a sustainable adsorbent for removing PCs from wastewater. Biochar is reported to remove PCs from water with an average range of 58 to 91 %, depending on the nature of feedstock, pyrolysis conditions, and characteristics of the pharmaceuticals. Biochar's effectiveness is attributed to its unique properties, including high porosity, large surface area and diverse functional groups, which enable the adsorption of various pharmaceutical compounds through physical and chemical interactions. Common PCs such as tetracycline, ciprofloxacin, ibuprofen, paracetamol, sulfamethoxazole, and cephalexin can be effectively removed using biochar. The adsorption process involves different mechanisms such as Van der Waals forces, electrostatic interactions, hydrogen bonding, and surface complexation. This review summarizes the current state of knowledge on biochar-based adsorption mechanisms, highlights successful applications in wastewater treatment, and identifies areas for future research. While promising, a deeper understanding of adsorption mechanisms, optimization of biochar production, and the development of effective regeneration methods are crucial for maximizing biochar's efficacy and ensuring its sustainable implementation in wastewater treatment systems.