Related Experiment Video
Updated: Jun 25, 2026

Synthesis of Zeolites Using the ADOR Assembly-Disassembly-Organization-Reassembly Route
Published on: April 3, 2016
Exploiting in situ NMR spectroscopy to understand non-traditional methods for zeolite synthesis
Nicole L Kelly1, Emma A L Borthwick1, Gaynor B Lawrence1
1School of Chemistry, EaStCHEM and Centre of Magnetic Resonance, University of St Andrews North Haugh St Andrews KY16 9ST UK rem1@st-andrews.ac.uk sema@st-andrews.ac.uk.
Non-traditional zeolite synthesis mechanisms were explored using simultaneous in situ liquid- and solid-state 29Si NMR spectroscopy. This method revealed intercalated species and their role in forming zeolitic connections over time.
Area of Science:
- Materials Science
- Chemistry
- Spectroscopy
Background:
- Zeolite formation mechanisms are primarily studied via hydrothermal methods.
- Non-traditional synthesis routes yield novel materials but have poorly understood mechanisms.
Purpose of the Study:
- To elucidate the formation mechanism of zeolites from layered silicate precursors using advanced spectroscopic techniques.
- To identify key intermediates and reaction pathways in non-traditional zeolite synthesis.
Main Methods:
- Simultaneous in situ liquid- and solid-state 29Si Nuclear Magnetic Resonance (NMR) spectroscopy.
- Tracking species evolution over time during zeolite formation.
Main Results:
- Provided evidence for specific species intercalated into the layered silicate precursor.
- Identified species responsible for building inter-layer, zeolitic connections.
- Established the temporal evolution of these species during zeolite formation.
Conclusions:
- Simultaneous in situ liquid- and solid-state 29Si NMR is effective for mechanistic studies of zeolite formation.
- The study clarifies the role of intercalated species in constructing zeolite frameworks from layered precursors.
More Related Videos
09:46Adsorption Device Based on a Langatate Crystal Microbalance for High Temperature High Pressure Gas Adsorption in Zeolite H-ZSM-5
Published on: August 25, 2016
08:55High-Temperature and High-Pressure In situ Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy
Published on: October 9, 2020
Related Concept Videos
NMR Spectroscopy and Mass Spectrometry of Aldehydes and Ketones
NMR Spectroscopy of Aromatic Compounds
NMR Spectroscopy: Chemical Shift Overview
For instance, the proton...
Applications Of NMR In Biology
The...
NMR Spectroscopy Of Amines
2D NMR: Overview of Heteronuclear Correlation Techniques