Uranium Extraction from Seawater: A Novel Approach Using Aluminum Fumarate-Based Metal-Organic Framework Aerogels

Efficient extraction of uranyl ions from seawater is crucial for the commercialization of nuclear technology. Metal-organic frameworks (MOFs), with their superior uranium extraction properties, face challenges in large-scale applications due to their powdery nature and the difficulty of assembling them into mechanically stable macroscopic composites. To address this, successfully synthesized 90 wt % nanoMOF (aluminum fumarate) loaded directional aerogels (AlFA-3-10) using polyvinyl alcohol (PVA) as an adhesive, which demonstrates robust strength longitudinally and transversely. Our uranium adsorption experiments reveal that at a pH of 8 (akin to that of seawater), the AlFA-3-10 achieves a maximum adsorption capacity of 1146.25 mg g^-1, maintaining this exceptional performance over five cycles. Notably, in simulated seawater, AlFA-3-10 exhibits high selectivity for uranyl ions with minimal interference from other ions. The directional pores within AlFA-3-10 facilitate fluid transmission and exchange, ensuring optimal contact between the MOF and uranyl ions, thereby enhancing electrostatic attraction and electron transport for improved capture efficiency. This streamlined approach maximizes the intrinsic potential of nano-MOFs and heralds a new era for their integration into macroscopic composite materials.