Mapping Source-Specific Air Pollution Exposures Using Positive Matrix Factorization Applied to Multipollutant Mobile...

Mobile monitoring strategies are increasingly used to provide fine spatial estimates of multiple air pollutant concentrations. This study demonstrates a novel approach using positive matrix factorization (PMF) applied to multipollutant mobile monitoring data to assess source-specific air pollution exposures and to estimate associated emission factors. Data were collected from one-year mobile monitoring, with an average of 26 repeated measures of size-resolved particle number counts (PNC), PM_2.5, BC, NO₂, and CO₂ at 309 sites in Seattle from 2019 to 2020. PMF was used to characterize underlying source-related factors. The sources associated with these six factors included emissions from aviation, diesel trucks, gasoline/hybrid vehicles, oil combustion, wood combustion, and accumulation mode aerosols. Fuel-based emission factors for three transportation-related sources were also estimated. This study reveals that PNC of ultrafine particles with size <18, 18-42, and 42-178 nm was dominated by features associated with aircraft, diesel trucks, and both oil and wood combustion. Gasoline and hybrid vehicles contributed the most to CO₂ and NO₂ concentrations. This approach can also be extended to other metropolitan areas, enhancing the exposure assessment in epidemiology studies.