An Environmental Engineering Study Case: Constructing Cataluminescence Sensors Based on Octahedral Nanocomposites for...

Isovaleraldehyde is an important chemical raw material for the production of flavors, which is volatile and flammable and poses a health risk to humans. It is, therefore, essential to develop a rapid assay for the identification of isovaleraldehyde. In this study, octahedral NiCo₂O₄/MIL-Fe₅₃ nanocomposites were successfully fabricated for the rapid detection of isovaleraldehyde. The prepared NiCo₂O₄/MIL-Fe₅₃ nanocomposites were characterized by SEM, XRD, FTIR, and XPS to analyze the material properties. The effects of temperature, carrier gas flow rate, selectivity, and stability on the cataluminescence performance of this sensor were investigated. The results showed that NiCo₂O₄/MIL-Fe₅₃ nanocomposites have excellent selectivity to isovaleraldehyde with response and recovery times of 6 and 8 s, respectively. A linear relationship was found between the CTL signal and isovaleraldehyde concentration Y = 9.56X - 23.3 (R² = 0.99) over the concentration range of 13.66 to 437.22 ppm with a detection limit of 2.44 ppm. The relative deviation RSD = 4.18% for multiple tests of the sensor indicates good stability and longevity. Mechanistic studies have shown that the heterojunction formed by NiCo₂O₄/MIL-Fe₅₃ nanocomposites has the advantage of improving CTL sensing performance. This study may advance the application of cataluminescence sensors in the detection of isovaleraldehyde.