Synthesis of Fe₃O₄@MCM-48 as Nano Fertilizer for Growth Stimulation in Tomato Plants

Innovative nano fertilizers based on nanoparticles present great potential for agriculture since they can stimulate growth and development in different crops. However, the efficiency of nanoparticles directly depends on their physicochemical characteristics, such as composition, shape, size, and the type of plant species. In this work, a material formed by mesoporous silica and iron oxide (Fe₃O₄@MCM-48) was synthesized and used as a nano fertilizer for tomato crop. Materials with different percentages of iron (10, 20, 30, 40, and 50% by weight) were applied to study the effect of the amount of iron in the plants and compared with MCM-48 without iron and ferric chloride hexahydrate. Using X-ray diffraction (XRD), it was possible to identify the phases present in the system, and with Transmission Electron Microscopy (TEM), it was observed that the material is made up of a matrix of MCM-48 with embedded Fe₃O₄ nanoparticles with a size of 5 nm. Also, the results show that all treatments with nano fertilizers increased the content of photosynthetic pigments and carotenoids in leaves. The use of nano fertilizers can be a viable option to improve the crop growth and efficiency of nutrient use in plants.