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One-step functionalization of gold nanorods with N-heterocyclic carbene ligands
Nathaniel L Dominique1, Phattananawee Nalaoh2, David M Jenkins2
1Department of Chemistry and Biochemistry, University of Notre Dame Notre Dame Indiana 46556 USA jcamden3@nd.edu.
RSC Advances
|February 17, 2025
Abstract:
Here, we present a one-step approach to append N-heterocyclic carbenes (NHCs) to gold nanorods. The nanorods are treated with NHC gold or silver complexes in a mixture of water and dichloromethane. Surface-enhanced Raman spectroscopy and mass spectrometry characterization reveals that this procedure results in a ligand transfer yielding chemisorbed NHCs.

