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Updated: May 27, 2025
Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Unlocking New Frontiers: Photo-Isomerism and Magnetic Properties in Multifunctional Hetero-Tetra-Metallic Complexes
Ingrid Suzana1, Jérémy Forté1, Sébastien Pillet2
1IPCM-CNRS, UMR 8232, Sorbonne Université, 4 Place Jussieu, 75252, Paris Cedex 05, France.
Abstract:
Hetero-tetra-metallic complexes, FeNOCuLnCo (Ln=Gd, Tb, Dy), combining magnetic properties and photo-isomerism, were obtained through the rational assembly of the photo-switching nitroprusside anion FeNO with new magnetic Schiff base CuLnCo precursors. Herein, we describe the synthesis and characterisation of these compounds followed by a demonstration of their multifunctional character. Particularly noteworthy is the FeNOCuTbCo complex which is one of the few examples of a photo-isomerisable SMM.
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