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Programmable assembly/disassembly of metal-organic cage integrated 2D nanosheets
Vellaiyadevan Sivalingam1, Dillip Kumar Chand1
1IoE Center of Molecular Architecture, Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India. dillip@zmail.iitm.ac.in.
Chemical Communications (Cambridge, England)
|February 18, 2025
Abstract:
This work demonstrates a stepwise assembly process to prepare [Pd(Pd2L4)]-type 2D nanosheets using Pd(II) and a stoichiometry-controlled metal-organic cage of Pd2L4 type. A convenient design strategy for dynamic interconversion between cage-based 2D nanosheets and well-defined monomeric cages is achieved.
