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Updated: May 27, 2025

Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyltroponeiron
Published on: August 12, 2019
Intermolecular N-N Coupling of a Dinitrosyl Iron Complex Induced by Hydrogen Bond Donors in the Secondary
Kayla M Fugami1, Gabriel S Black1, Tim Kowalczyk1
1Department of Chemistry, Western Washington University, Bellingham, Washington 98225, United States.
Abstract:
The intermolecular N-N coupling of NO in a dinitrosyl iron complex (DNIC) induced by hydrogen bond donors in the secondary coordination sphere to form N2O is reported. A family of complexes containing pendant anilines in the secondary coordination sphere were synthesized and characterized. Reduction of the {Fe(NO)2}9 complex [Fe(PhNHPDI)(NO)2][BPh4] (3) to the {Fe(NO)2}10 Fe(PhNHPDI)(NO)2 (4) results in intermolecular N-N coupling to form N2O. Similar reactions of the control {Fe(NO)2}9 complex [Fe(PhNMePDI)(NO)2][BPh4] (7), which does not have H-bonding groups in the secondary coordination sphere, do not result in N2O formation. The hydrogen bonding capabilities of the complexes were explored spectroscopically and computationally.
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