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Updated: May 27, 2025

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Parity-time-reversal symmetry-breaking transitions in polymeric systems
Tanmoy Pal1, Ranjan Modak2, Bhabani Prasad Mandal3
1University of Toronto, Department of Biochemistry, Toronto, Ontario M5S 1A8, Canada.
Abstract:
We show that classical DNA unzipping transition, which is equivalently described by quantum mechanical localization-delocalization transition in the ground state of non-Hermitian single impurity Hatano-Nelson Hamiltonian, is underpinned by generalized parity (P)-time reversal (T) symmetry breaking transition. We also study one-dimensional discretized version of the Hatano-Nelson model in the presence of single impurity and random disorder on a finite-size lattice. These discrete models are useful to study unzipping of a single adsorbed polymer from a surface. Our results show that the discrete models also undergo a phase transition from a PT unbroken phase to a broken phase. Interestingly, the generalized PT phase transition points coincide with the localization-delocalization transition for continuum as well as lattice models.
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