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An Ambiphilic Phosphide with Three Different Coordination Modes to Group 7-10 Metals

Adrien T Normand1, Hélène Cattey1, Marie-José Penouilh1

  • 1Institut de Chimie Moléculaire de L'Université de Bourgogne (ICMUB), 9 avenue Alain Savary, 21000 Dijon, France.

Inorganic Chemistry
|February 20, 2025
PubMed
Summary

New phosphide anions, bis(thiophosphoranyl)phosphide (BTPP), coordinate to transition metals. These complexes exhibit diverse coordination modes and geometries, with applications in single-molecule magnets and catalysis.

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