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Updated: May 27, 2025

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3D Printing and In Situ Surface Modification via Type I Photoinitiated Reversible Addition-Fragmentation Chain Transfer Polymerization
Published on: February 18, 2022
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Photoreaction Drives Efficient, Precise, and Sustainable Additive Manufacturing
Jinghan Hu1, Dan Wang1, Haiyan Peng1,2,3
1Key Lab of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China.
Chem & Bio Engineering
|February 20, 2025
Summary
Three-dimensional (3D) printing, or additive manufacturing, excels in creating complex structures. Vat photopolymerization advances efficiency and accuracy, though challenges in functional and multimaterial printing persist.
Area of Science:
- Materials Science
- Engineering
- Chemistry
Background:
- Additive manufacturing (3D printing) offers advanced capabilities for complex product creation.
- Vat photopolymerization is a key 3D printing technology known for speed, precision, and formulation ease.
Purpose of the Study:
- To highlight recent advances in photopolymerization-based 3D printing.
- To discuss improvements in printing efficiency, accuracy, and sustainability.
- To identify future challenges and opportunities in high-performance additive manufacturing.
Main Methods:
- Review of photoreaction design strategies in photopolymerization.
- Analysis of breakthroughs in monomers, photoinitiating systems, and light sources.
- Discussion of advancements promoting printing efficiency and accuracy.
Main Results:
- Significant progress has been made in enhancing printing speed and precision.
- Photoreaction design has driven innovations in photopolymerizable materials and systems.
- Sustainability aspects of vat photopolymerization are being increasingly addressed.
Conclusions:
- Vat photopolymerization is a rapidly advancing 3D printing technology.
- Future research should focus on longer-wavelength printing, functional materials, and multimaterial printing.
- Addressing these challenges is crucial for next-generation high-performance additive manufacturing.

