Synergistically driven PdCo alloy based on cross-linked carbon dots for efficient formic acid dehydrogenation

Modifying the electronic structure of precious metals by alloying with non-precious metals is a proven strategy for enhancing the performance of dehydrogenation catalysts. In this work, a PdCo alloy catalyst supported on N-doped carbon dots (NCDs) was synthesized using a straightforward hydrothermal and reduction process. This catalyst effectively promoted the dehydrogenation of formic acid without the need for any additives at 323 K. The confinement effect of NCDs facilitated the formation of uniformly dispersed PdCo alloy particles (average size of 2.7 nm). X-ray photoelectron spectroscopy analysis revealed that the addition of Co not only increases the electron density of Pd but also enhances the electronic support from the electron-rich N atoms in NCDs, thereby significantly improving catalytic activity. Through optimization of the Pd-to-Co molar ratio, it was determined that Pd₉Co₁/NCDs exhibited superior activity for formic acid dehydrogenation. The turnover frequency of the catalyst was 593 h^-1 and the activation energy of the dehydrogenation process was 39.3 kJ·mol^-1. This research established an experimental basis for designing noble metal-based catalysts with enhanced catalytic efficiency.