Unveiling the environmental sustainability of Ti₄O₇ electrified membrane for perfluorooctanoic acid removal

Emerging electrified membrane (EM) technology offers an efficient approach for decentralized water purification. However, EM currently faces the challenge of unknown environmental sustainability, which presents a critical knowledge gap impeding its scale-up implementation. In this work, we aim to explore the environmental impacts of EM technology via a "cradle-to-grave" life cycle assessment, benchmarked against sequential ultrafiltration-nanofiltration. Our study found that the current EM technology shows higher greenhouse gas (GHG) emissions (19.70 kgCO₂e g^-1) than ultrafiltration-nanofiltration (8.60 kgCO₂e g^-1) for micropollutants removal. Electro-filtration operation dominates the total environmental impacts of EM process, driven primarily by the supporting electrolyte and electricity consumption. Notably, transitioning to greener electrolytes at lower concentrations can reduce GHG emissions by up to 66%, while switching to low-carbon-grid electricity through renewable energy sources will achieve a 33% reduction. Overall, this work enhances understanding of the environmental impacts of EM technology, emphasizing electrolyte optimization and carbon-intensity-reduction of electricity as critical factors for its sustainable development.